1. Mahou Shoujo Madoka
Shaft at its finest, art style was perfect for this show, music, atmosphere too. They created great work from the typical Mahou Shoujo style. It had its flaws( KB being a being from other planet for example, it just felt wrong). It somehow reminded me of Faust.
2. Steins Gate
I don't know if this should be that high, because first two episodes were one of worse introductional episodes ever. Everything that happened after those two made up for it flaws.
3. Fate zero
Quality, Near-perfect reconstruction of original work, quality, great battles and interesting plot, quality. and quality.
4. Chihayafuru
I don't know what to write here that wouldn't spoil anything but this series is great.
5. Mirai Nikki
Great idea, batshit insane yandere and interesting cast. Main character is a bit too much of a wuss, that's why it isn't higher.
6. Gosick/Dantalian no shoka
7. Gosick/Dantalian no shoka
Goscik
detective show, with very interesting cases, love story all set in the great timeframe.. and in europe too. very fun to watch.
Dantalian
post WW2 era, or so it seems. another mystery show, different from gosick, with great atmosphere - can't decide which one of those two shows is better.
8. Horizon
It starts as clusterfuck, you've got no idea who is who and WTF is going on there..then, after you get to know the cast it gets very good, interesting. Fights are great - or, rather, debate fighting.
9. Tiger and Bunny
Title is weird, heores seem awkwardly designed, but it is really fun show based around great concept for the world.
10. Mazinkaizer SKL
The dumb as fuck action show of the year..still - very entertaining.