Ehhhh not really. Anime plays out the same as it did in the manga with him just literally being there out of nowhere. I love though that he's such a badass that pointing a pistol (which at this point in the game with super elemental fruit powers and cyborg spitting lasers is probably the least intimidating thing you can do) gets Kizaru to stand down.

Guess he must be packing some super haki bullets or something.