Orokamono:
Episode 436 - Yibis
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There wasn't a single moment during this fight that Luffy would have had my sympathies. While I'm all for saving Ace, at least he should think every now and then if getting himself killed is really helping Ace at all. After answering such a simple question he could do already much wiser things than in this episode. I know Luffy is a hopeless idiot but nobody is that stupid. Honestly. Especially considering how he knew beforehand Magellan is poisonous (Mr. 2 told him) and he should have realised based on his experience that fighting logia types isn't that easy (though that he might not have noticed so early but it would still allowed him to try to escape or come up with a better plan).