Power levels in Bleach have always been pretty shaky. Since everyone tends to use fancy tricks in addition to raw power we often see situations where the fancy trick would allow instant victroy if used a certain way, but it's rarely used that way. Cases in point:

When Byakuya uses his Senbonzakura he's shown that he has control over the motion of the cloud. Now if he can control all those tiny blades he should be able to focus them and use them to cut people in half instead of just making huge numbers of surface wounds.

When Tousen traps Kenpahi in his bankai Kenpahi couldn't really do anything until Tousen touched him. If Tousen lined up his sword on Zaraki's heart and made a thrust at full speed he should have been able to kill him. Even if that didn't work, he would have been able to try again from different directions, each time cutting up important parts of Kenpachi's body. Or he could have just cut his head off from the beginning. You can't really turn a decapitating strike into something non fatal in the time frame Zaraki was working in to make Tousen's strikes less damaging.

That being said, Kenpashi's raw physical power is also tremendous, considering he pushed his sword right through Ichigo's. The same sword that shattered Jidanbou's Axes and took Gin's Shinso without breaking.

Ichigo's superspeed should allow him to remove heads before people know what happened (though his speed has been rendered pretty worthless as people with just training and power have repeatedly shown they can keep up with it).

All in all the techniques people have generally could determine the outcome of these battles, the problem is, they rarely do. Instead the right character just wins because they are the on who is supposed to win. If Byakuya or Kenpachi were to fight an Arrancar they would probably lose if Ichigo was nearby and on his way to save the day. But if it was just the Captain and the Arrancar, then the Captain would likely be victorious for being on the good guy team.